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101.
SUN Leigang WANG Shaoqiang Robert A. MICKLER CHEN Jinghua YU Quanzhou QIAN Zhaohui ZHOU Guoyi MENG Ze 《资源与生态学报(英文版)》2019,10(2):112-126
The accurate measurement of the dynamics of photosynthesis in China’s subtropical evergreen forest ecosystems is an important contribution to carbon (C) sink estimates in global terrestrial ecosystems and their responses to climate change. Eddy covariance has historically been the only direct method to assess C flux of whole ecosystems with high temporal resolution, but it suffers from limited spatial resolution. During the last decade, continuous global monitoring of plant primary productivity from spectroradiometer sensors on flux towers and satellites has extended the temporal and spatial coverage of C flux observations. In this study, we evaluated the performance of two physiological remote sensing indices, fluorescence reflectance index (FRI) and photochemical reflectance index (PRI), to measure the seasonal variations of photosynthesis in a subtropical evergreen forest ecosystem using continuous canopy spectral and flux measurements in the Dinghushan Nature Reserve in southern China. The more commonly used NDVI has been shown to be saturated and mainly affected by illumination (R2=0.88, p < 0.001), but FRI and PRI could better track the seasonal dynamics of plant photosynthetic functioning by comparison and are less affected by illumination (R2=0.13 and R2=0.51, respectively) at the seasonal scale. FRI correlated better with daily gross primary production (GPP) in the morning hours than in the afternoon hours, in contrast to PRI which correlated better with light-use efficiency (LUE) in the afternoon hours. Both FRI and PRI could show greater correlations with GPP and LUE respectively in the senescence season than in the recovery-growth season. When incident PAR was taken into account, the relationship between GPP and FRI was improved and the correlation coefficient increased from 0.22 to 0.69 (p < 0.001). The strength of the correlation increased significantly in the senescence season (R 2=0.79, p < 0.001). Our results demonstrate the application of FRI and PRI as physiological indices for the accurate measurement of the seasonal dynamics of plant community photosynthesis in a subtropical evergreen forest, and suggest these indices may be applied to carbon cycle models to improve the estimation of regional carbon budgets. 相似文献
102.
地理“大数据”的出现为研究城市问题提供了新的契机。基于兴趣点(POI)和位置服务(LBS)的地理“大数据”,采用空间计量模型、数理统计分析等方法,尝试探讨了长江中游城市群城市活力水平及其影响因素。结果表明:①长江中游城市群城市活力整体处于较低水平,武汉、南昌和长沙中心地位突出,城市群边缘形成片状活力“洼地”的空间格局;②长江中游城市群城市活力与经济发展水平存在耦合关系,低度耦合城市少,较高度耦合和高度耦合城市较多;③高校资源、经济密度、基础设施水平和信息化程度4个因素是影响长江中游城市群城市活力的主要因素,各因素的影响效应具有空间异质性。 相似文献
103.
长三角工业区夏季近地层臭氧和颗粒物污染相互关系研究 总被引:4,自引:0,他引:4
利用2013年5月15日到8月31日南京江北工业区(长三角典型工业区)同步的观测资料分析了近地层臭氧(O3)和细颗粒物(PM2.5)、气溶胶光学厚度(AOD)的变化特征及相互间的关系,并结合光化学箱模式分析了AOD对近地层O3生成的影响。结果表明,观测期间PM2.5平均质量浓度为56.2±20.1 μg m-3;AOD(500 nm)均值为1.4±0.9;波长指数α(440~870 nm)均值为1.0±0.3。PM2.5质量浓度24 h均值超国家二级标准20.2%,超标时AOD均值增加14.7%,α平均值增加23.9%,O3体积分数均值减少12.3%。O3超国家二级标准10.1%,超标时段AOD增加34.9%,α变化不显著。高温低湿条件下,O3日变化峰值(y)和PM2.5质量浓度(x)存在较高的线性相关。相对湿度<60%时,两者拟合曲线为y=0.97x+43.96(拟合度R2=0.60),温度>32°C时,两者拟合方程为y=1.24x+30.61(R2=0.64)。夏季长三角工业区呈现高浓度O3与高浓度PM2.5叠加的大气复合污染。O3日变化峰值和AOD变化呈显著负相关。模拟结果显示,O3日变化峰值(y)和AOD(x)呈现极高的负相关[y=-34.28x+181.62,R2 = 0.93或y=220.62·exp (-x/3.17)-19.50,R2=0.99]。 相似文献
104.
Min XUE Jianzhong MA Guiqian TANG Shengrui TONG Bo HU Xinran ZHANG Xinru LI Yuesi WANG 《大气科学进展》2021,38(7):1209-1222
Photochemical smog characterized by high concentrations of ozone (O3) is a serious air pollution issue in the North China Plain (NCP) region, especially in summer and autumn. For this study, measurements of O3, nitrogen oxides (NOx), volatile organic compounds (VOCs), carbon monoxide (CO), nitrous acid (HONO), and a number of key physical parameters were taken at a suburban site, Xianghe, in the NCP region during the summer of 2018 in order to better understand the photochemical processes leading to O3 formation and find an optimal way to control O3 pollution. Here, the radical chemistry and O3 photochemical budget based on measurement data from 1-23 July using a chemical box model is investigated. The daytime (0600-1800 LST) average production rate of the primary radicals referred to as ROx (OH + HO2+ RO2) is 3.9 ppbv h-1. HONO photolysis is the largest primary ROx source (41%). Reaction of NO2 + OH is the largest contributor to radical termination (41%), followed by reactions of RO2 + NO2 (26%). The average diurnal maximum O3 production and loss rates are 32.9 ppbv h-1 and 4.3 ppbv h-1, respectively. Sensitivity tests without the HONO constraint lead to decreases in daytime average primary ROx production by 55% and O3 photochemical production by 42%, highlighting the importance of accurate HONO measurements when quantifying the ROx budget and O3 photochemical production. Considering heterogeneous reactions of trace gases and radicals on aerosols, aerosol uptake of HO2 contributes 11% to ROx sink, and the daytime average O3 photochemical production decreases by 14%. The O3-NOx-VOCs sensitivity shows that the O3 production at Xianghe during the investigation period is mainly controlled by VOCs. 相似文献
105.
Acetaldehyde is one of the important VOC species of O3 precursors in the atmospheric environment. The influences of relative humidity (RH) and initial VOC/NOx ratio (RCN) on the formation of O3 are studied in smog chamber experiments, and the MCM v3.3.1 mechanism of acetaldehyde is modified based on the experimental results. In low-RH conditions (RH= 11.6%±1.1%), the O3 concentration at 6 h increases first and then decreases with the increase of RCN, and the RCN at the inflection point of O3 concentrations is 3.2. In high-RH experiments (RH = 78.8%±1.0%), variation of the O3 concentration at 6 h with RCN is similar to that in low-RH experiments, but the RCN at the inflection point is 2.8. RH has no significant effect on the O3 concentrations under low RCN (< 3), whereas it has a negative effect under high RCN (> 3). Compared with the experimental results, original MCM v3.3.1 greatly underestimates the O3 concentrations. Addition of both the photolysis process of peroxyacetyl nitrate and the photolysis process of HNO3 on the reactor surface into the original MCM can reduce the difference between the simulated O3 concentrations and the experimental results at 6 h from 24%-35% and 17%-49% to 6%-26% and 10%-42% under low- and high-RH conditions, respectively. The maximum incremental reactivity (MIR) of acetaldehyde simulated with the modified MCM is 4.0 ppb ppb-1 without considering the effect of other VOCs. 相似文献
106.
亚甲基蓝在水体系中的光化学降解研究 总被引:1,自引:0,他引:1
研究水体系中亚甲基蓝的光化学降解.结果表明,在高压汞灯照射下,亚甲基蓝在人工海水中降解得最快,蒸馏水次之,而在天然海水中降解得最慢.通过对比研究发现.重金属离子(Cu2+,Zn2+,Cd2+,Hg2+)和腐殖酸能够在一定程度上抑制亚甲基蓝的光降解;而丙酮能促进亚甲基蓝的光降解.由此可见,重金属离子和腐殖酸可能是造成亚甲基蓝在天然海水中降解缓慢的主要因素之一. 相似文献
107.
天然水环境中的溶解有机物及其光化学降解对重金属生物可利用性的影响 总被引:1,自引:0,他引:1
溶解有机物(DOM)在控制水生生态系统的化学、生物和物理特性中起着重要的作用.DOM不仅能够结合黏土颗粒,而且也能结合对环境和生物有重要影响的Hg,Cu,Pb,Cd,Ni等重金属和有机污染物,从而改变这些物质的迁移、生物可利用性和毒性.本文综述了天然水环境中DOM与重金属的相互作用和对其生物可利用性的影响,并对影响DOM光化学降解的因素及其对重金属生物可利用性的影响做了总结.已有的研究表明:DOM的结构、分子量、浓度、重金属种类、水环境条件等均会影响到DOM与重金属污染物的相互作用;光化学降解会显著改变DOM与重金属的相互作用,从而使其生物可利用性发生变化. 相似文献
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110.
The photochemical degradation of triadimefon in seawater was investigated under different reaction conditions in this study. The results showed that triadimefon could be effectively degraded by the irradiation of a high-pressure mercury lamp and the photodegradation rotes were influenced by aquatic media, heavy metal ions and photosensitizers. The photochemical degradation of triadimefon followed the first-order reaction kinetic behavior, with the rate constants ranging from 0.0027 to 0.0128 min-1 under the studied conditions. The photolysis of triadimefon was slower in natural seawater than in distilled water or synthetic seawater. All the heavy metal ions studied in this paper had inhibition effects on the photolysis of triadimefon. Acetone, as a common photosensitizer, could accelerate the photolysis of triadimefon. Three photoproducts were identified by GC-MS analysis. Our study confirmed that photochemical degradation is an effective pathway to remove triadimefon in seawater. 相似文献